PhD Project: Dyes with Switchable Intersystem Crossing for Photonics

Job Description

DyeSICPhoto project aims develop a conceptually new type of functional dyes with programmable excited state behaviour and to unlock their practical potential in photonics. This will be achieved by optimization of the spin-orbit charge transfer intersystem crossing (SOCT-ISC) process in electron donor-acceptor molecules. In such systems, fluorescence and triplet state quantum yields depend on the charge transfer process and thus can be finely controlled. Dyes will be designed to operate either as bright fluorophores or photosensitizers transferring energy to other molecules, depending on environmental parameters, applied external stimuli, or activating species. In addition to having significant fundamental importance for understanding the photophysics of organic molecules this work will afford advanced molecular systems and materials with high added value for biophotonics and energy conversion. To demonstrate the potential in biophotonics we will use these systems as smart sensitizers for photomedical treatments and imaging probes for reactive oxygen species in living cells. Alternatively, new dyes will be used as components of multichromophoric assemblies capable of efficient light energy harvesting and conversion, for solar cells efficiency enhancement through the process of triplet-triplet annihilation upconversion.

Student requirement for this project
Minimum upper second-class degree (2.1) BSc degree in Chemical Sciences or equivalent.
Ideally the applicants will have demonstrated:
• desire to discovering new knowledge, genuine interest in chemistry and strong competence of organic chemistry
• creativity and ability to work with a high degree of independence
• training and/or laboratory experience in organic synthesis and spectroscopy
• good interpersonal and collaborative skills, commitment to work in diverse and multicultural groups
• good command of the English language, both written and spoken (minimum level required: 6.0 in the IELTS test)
• legal ability to travel within the EU (citizenship of EU, EAA or associated countries)
Experiences in photochemistry and photophysics are merits.

TU Dublin School of Chemical and Pharmaceutical Sciences

Details of funding
Fully Funded (scholarship, fees, materials)
Funding agency Science Foundation Ireland
Student Stipend per annum € 18500
Materials & Travel Budget per annum € 2000
Fees covered by the funding per annum € 4500
Duration of funding 48 months

If you are interested in submitting an application for this project, please complete an Expression of Interest available here: forms.office.com/Pages/ResponsePage.aspx?id=yxdjdkjpX06M7Nq8ji_V2hiTno1vZnVJip0jxPLsgu9UN0JWSjA5REk3M1FFTTFGSEwzVzNQNklJMS4u

Application deadline 2 September 2022